نوع مقاله : مقاله پژوهشی

نویسندگان

1 استاد دانشگاه پیام نور

2 کارشناس مسئول شیمی

3 گروه شیمی، دانشگاه پیام نور، ص.پ. ،57271-7079تهران، ایران

چکیده

در این پژوهش 1 و 2 –دی هیدروکسی-9 و 10-آنتراکینون (آلیزارین رد )، برای اولین بار به عنوان یک حسگر شیمیایی رنگ‌سنجی متوالی معرفی گردیده است که برای تشخیص و اندازه‌گیری متوالی مس دو ظرفیتی (Cu2+) و آرژنین (Arg) در محیط آبی مورد استفاده قرار می‌گیرد، فرآیند تشخیص دو مرحله‌ای

می باشد. واکنش آلیزارین رد (Aliz) و مس دو ظرفیتی در مرحله اول تغییر رنگ محسوس از نارنجی کمرنگ به بنفش کمرنگ را نشان می‌دهد، علاوه بر این واکنش بین (Aliz-Cu) و آرژنین تغییر رنگ محسوس را از بنفش کمرنگ به بنفش پررنگ را نشان می دهد.

نتایج نشان داد که آلیزارین رد و Aliz-Cu به ترتیب میل پیوندی قوی و حد تشخیص خوبی برای گونه‌های مس دو ظرفیتی و آرژنین را دارند. برای مس دو ظرفیتی، محدوده خطی و حد تشخیص 98/43-78/4، 43/0میکرومولاراست و برای آرژنین، محدوده خطی و حد تشخیص 78/107-15/7، 65/0 میکرومولار

می‌باشد. در نهایت با استفاده از این روش این دوگونه را با موفقیت در نمونه‌های واقعی (آب آشامیدنی در پادگان نظامی، آب معدنی و سرم خون سربازان) اندازه‌گیری کردیم.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Design and synthesis of simple, sensitive and selective colorimetric sensor for sequential determination of dual analytes, Cu2+ and arginine and its applications for measurement in drinking water in military barrack, mineral water and in the blood serum of soldiers

نویسندگان [English]

  • Hossein Tavallali 1
  • maryam sadat salami 2
  • Mohamad Ali Karimi 3
  • Abolfath Parhami 1

1 Professor of Payamenoor University

2 chemist

3 Department of Chemistry, Payame Noor University, 19395-4697 Tehran, Islamic Republic of Iran

چکیده [English]

In this research, 1 and 2-dihydroxy-9 and 10-anthraquinone ( Alizarin Red ) has been introduced for the first time as a sequential chemosensor to detect and measure Cu2+ and arginine in an aqueous medium. The reaction of Alizarin Red (Aliz) and Cu2+in the first step shows a noticeable change from pale orange to pale purple, in addition, in the second step the reaction between (Aliz-Cu) and arginine shows a noticeable color change from pale purple to deep purple.

The results showed that Alizarin Red and Aliz-Cu have strong binding affinity and good detection limit for Cu2+ and arginine, respectively. For Cu2+, the linear range and detection limit are 4.78-43.98, 0.43 μmol L−1, and for arginine, the linear range and detection limit are 7.15-107.78, 0.65 μmol L−1. Finally, by using this method, we successfully measured these two species in real samples (drinking water in military barrack, mineral water and in the blood serum of soldiers).

کلیدواژه‌ها [English]

  • Chemosensor
  • Alizarin Red
  • Cu2+
  • Arginine
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