Synthesis and evaluation the microstructure and electrochemical properties of rGO-ZIF-8 hybrid nanocoating created on aerospace steel
Pages 1-20
Seyed Ali Hosseini Moradi, Gholamreza Faghani
Abstract Pitting corrosion is one of the most destructive forms of localized corrosion in aerospace passive alloys such as steel and aluminum, and the presence of chloride ions accelerates the initiation and growth of this phenomenon.. The aim of this study is to synthesize a hybrid nanocomposite of reduced graphene oxide and a stable metal–organic framework with an eight-membered structure and to evaluate its performance in inhibiting pitting corrosion of steel through barrier and active inhibition mechanisms. The hybrid nanocomposite of reduced graphene oxide and the stable metal–organic framework with an eight-membered structure was synthesized via in situ growth on reduced graphene oxide sheets and characterized by Raman spectroscopy, X-ray diffraction, and field emission scanning electron microscopy. The corrosion resistance performance of reduced graphene oxide, the metal–organic framework, and the hybrid nanocomposite was evaluated in 3.5wt.% saline solution using electrochemical impedance spectroscopy and polarization measurements. Microstructural results indicated that the metal–organic framework nanoparticles with uniform polyhedral morphology grew on the reduced graphene oxide surface, forming a stable hybrid structure.Impedance tests showed that the hybrid nanocomposite provided the highest total resistance, reaching 4038 ohm.cm² after 35 hours of immersion. Moreover, polarization measurements demonstrated a significant reduction in corrosion current density and an increase in protection efficiency up to 83%. The superior performance of this system was attributed to the synergistic effect of the physical barrier of reduced graphene oxide and the controlled release of zinc ions and 2-methylimidazole from the metal–organic framework, simultaneously inhibiting anodic and cathodic reactions.







